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http://nopr.niscpr.res.in/handle/123456789/20029| Title: | Synthesis and crystal structure of a nido 11-vertex diplatinaundecaborane cluster [(μ-PPh2)(PPh3)2Pt2B9H7-9, 11-(Oipr)2] |
| Authors: | Wu, Li-Bin Dou, Jian-Min Guo, Qing-Liang Li, Da-Cheng Wang, Da-Qi |
| Issue Date: | Aug-2006 |
| Publisher: | NISCAIR-CSIR, India |
| IPC Code: | Int. Cl.8 C07F5/02 ; C07F15/00 |
| Abstract: | The nido 11-vertex diplatinaundecaborane [(μ-PPh2)(PPh3)2Pt2B9H7-9, 11-(Oipr)2] (3) has been obtained by the reaction of [PtCl2(PPh3)2] with B10H102- in the presence of iPrOH under solvothermal conditions and characterized by elemental analysis, spectroscopic, and X-ray diffraction studies. The title cluster belongs to triclinic, space group PI-, with the crystal cell parameters: a = 12.622(4) Å, b = 13.439(5) Å, c = 17.926(6) Å; α = 83.232(5)°, β= 75.952(4)°, γ = 67.577(4) °. The tie cluster (3) has a nido-eleven vertex {Pt2B9} polyhedral skeleton with two Pt atoms at the neighbouring position of the open Pt2B3 face. Two Pt atoms are bridged by a PPh2 group. The H atoms at B (9) and B(11) positions are substituted by Oipr groups, respectively. |
| Page(s): | 1840-1843 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.45A(08) [August 2006] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 45A(8) 1840-1843.pdf | 885.88 kB | Adobe PDF | View/Open |
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