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http://nopr.niscpr.res.in/handle/123456789/20036| Title: | Synthesis and structural characterisation of two Mn(II) complexes with 2,4,6-tris(2-pyridyl)-l ,3,5 -triazine ligand: Effect of weak interactions in their packing diagrams |
| Authors: | Das, Anamika Pilet, Guillaume Mitra, Samiran |
| Issue Date: | Sep-2006 |
| Publisher: | NISCAIR-CSIR, India |
| IPC Code: | Int.Cl.8: C07F13/00 |
| Abstract: | Two neutral monomeric complexes of [Mn(tptz)(NO3)(Cl)(H2O)]· 0.5 H2O 1, Mn(tptz) (NCS)2(H2O)] 2 {tptz = 2,4,6-tris(2-pyridyl)- 1,3,5-triazine} have been synthesized and structurally characterized by single crystal X -ray diffraction and spectroscopic study. The structural analysis reveals that the nitrate anion is linked to Mn(II) as bidentate ligand in 1 and two thiocyanate anions are linked to metal ion through N-atoms in 2. The monomeric species of complexes 1 and 2 undergo H-bonding resulting in supramolecular 1D and 2D architectures respectively. |
| Page(s): | 1988-1993 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.45A(09) [September 2006] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 45A(9) 1988-1993.pdf | 1.22 MB | Adobe PDF | View/Open |
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