Horseradish peroxidase catalyzed and electrochemical oxidations of 2-thiouracil — A comparison

Goyal, Rajendra N; Sondhi, Sham M; Lahoti, Anand M; Abdulla, Adil A

Welcome to NIScPR Online Periodicals Repository

You can now access full text articles from research journals published by CSIR-NIScPR! Full text facility is provided for all nineteen research journals viz. ALIS, AIR, BVAAP, IJBB, IJBT, IJCA, IJCB, IJCT, IJEB, IJEMS, IJFTR, IJMS, IJNPR, IJPAP, IJRSP, IJTK, JIPR, JSIR & JST. NOPR also hosts three Popular Science Magazines viz. Science Reporter (SR), Vigyan Pragati (VP) & Science Ki Duniya (SKD) and a Natural Products Repository (NPARR).

Please use this identifier to cite or link to this item: http://nopr.niscpr.res.in/handle/123456789/20094

Full metadata record

DC Field	Value	Language
dc.contributor.author	Goyal, Rajendra N	-
dc.contributor.author	Sondhi, Sham M	-
dc.contributor.author	Lahoti, Anand M	-
dc.contributor.author	Abdulla, Adil A	-
dc.date.accessioned	2013-07-25T08:41:47Z	-
dc.date.available	2013-07-25T08:41:47Z	-
dc.date.issued	2005-03	-
dc.identifier.issn	0975-0975(Online); 0376-4710(Print)	-
dc.identifier.uri	http://hdl.handle.net/123456789/20094	-
dc.description	463-468	en_US
dc.description.abstract	Horseradish peroxidase (type VIII) catalyzed and electrochemical oxidations of 2-thiouracil have been studied in phosphate buffer of pH 7.20 (μ==1.0 M) at an ambient temperature of 25±2°C. The peroxidase catalyzed oxidation has been initiated by using hydrogen peroxide and electrooxidation carried out at pyrolytic graphite electrode. The UV-absorbing intermediates generated in both the oxidations have been characterized by voltammetry, spectrophotometry and by kinetics of decay and are found identical. Products of enzymic and electrochemical oxidations have been characterized by using GCMS stuides. A tentative redox scheme has been proposed for the enzymic oxidation of 2-thiouracil and compared with that of electrooxidation and has also been found similar. Thus, it has been concluded that oxidation of 2-thiouracil by enzymic and electrochemical methods are, in a chemical sense, identical.	en_US
dc.language.iso	en_US	en_US
dc.publisher	NISCAIR-CSIR, India	en_US
dc.relation.ispartofseries	Int.Cl.⁷ C25B3/02; C07B33/00	en_US
dc.rights	CC Attribution-Noncommercial-No Derivative Works 2.5 India	en_US
dc.source	IJC-A Vol.44A(03) [March 2005]	en_US
dc.title	Horseradish peroxidase catalyzed and electrochemical oxidations of 2-thiouracil — A comparison	en_US
dc.type	Article	en_US
Appears in Collections:	IJC-A Vol.44A(03) [March 2005]

Files in This Item:

File	Description	Size	Format
IJCA 44A(3) 463-468.pdf		1.51 MB	Adobe PDF	View/Open

Show simple item record