Please use this identifier to cite or link to this item: http://nopr.niscpr.res.in/handle/123456789/20220
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dc.contributor.authorYe, Cheong May-
dc.contributor.authorAriffin, Azhar-
dc.contributor.authorKhan, Mohammad Niyaz-
dc.date.accessioned2013-07-30T11:53:57Z-
dc.date.available2013-07-30T11:53:57Z-
dc.date.issued2005-10-
dc.identifier.issn0975-0975(Online); 0376-4710(Print)-
dc.identifier.urihttp://hdl.handle.net/123456789/20220-
dc.description2055-2059en_US
dc.description.abstractThe nucleophilic second-order rate constant (kOH) for the reaction of OHˉ with Nˉ benzylphthalimide appears to follow a reaction mechanism similar to that for reactions of OHˉ with phthalimide and its N-alkylphthalimides. The rate of hydrolysis reveals an insignificant contribution of water-catalysed cleavage of NBPT compared with its hydroxide ion catalysed reaction. The observed pseudo first-order rate constant, kobs for alkaline hydrolysis of NBPT decreases with increase in the content of organic cosolvents (up to 70%, v/v) in mixed water-CH3CN and water-DMF solvents.en_US
dc.language.isoen_USen_US
dc.publisherNISCAIR-CSIR, Indiaen_US
dc.relation.ispartofseriesInt. Cl.7 C07B41/00en_US
dc.rights CC Attribution-Noncommercial-No Derivative Works 2.5 Indiaen_US
dc.sourceIJC-A Vol.44A(10) [October 2005]en_US
dc.titleSolvent effects on alkaline hydrolysis of N-benzylphthalimide in mixed water-acetonitrile and mixed water-N,N-dimethylformamideen_US
dc.typeArticleen_US
Appears in Collections: IJC-A Vol.44A(10) [October 2005]

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