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http://nopr.niscpr.res.in/handle/123456789/20279| Title: | Synthesis, X-ray structural characterization and solution studies of a mononuclear Ni(II)-Schiff base complex bearing free formyl groups |
| Authors: | Gupta, Shankareswar Panja, Anangamohan Shaikh, Nizamuddin Goswami, Sanchita Banerjee, Pradyot Butcher, Ray J |
| Issue Date: | Jan-2004 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | A new mononuclear Ni(II)-Schiff base complex has been synthesized and structurally characterized through X-ray crystallography. The compound crystallizes in the monoclinic space group C2/c (No.15) with a = 17.268(7), b =14.619(6) and c = 10.683(4)Å. The molecular structure shows that the Ni(II) ion is in the distorted octahedral environment in which two phenolic oxygen atoms occupy the axial positions. Two -CHO groups arising out of the 2,6-diformyl-4-methylphenol remain as pendants. UV/vis and cyclic voltammetric experiments have been performed of the Ni(II) complex in DMF solution and the results compare well with the previously reported systems. |
| Page(s): | 63-66 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.43A(01) [January 2004] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 43A(1) 63-66.pdf | 412.85 kB | Adobe PDF | View/Open |
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