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http://nopr.niscpr.res.in/handle/123456789/20434| Title: | Silyl nitrogen compound: Part XV — Reactions of nonmetal halides with silylated tosylhydrazines |
| Authors: | Vasisht, S K Sharma, Anuradha |
| Issue Date: | Oct-2004 |
| Publisher: | NISCAIR-CSIR, India |
| IPC Code: | Int. Cl. 7 C0F 7/10 |
| Abstract: | Nonmetal halides EXn (E = C, Si, P, As, S; X = Br, Cl) and halogens (X= Br2,I2) react with bis(trimethylsilyl)tosylhydrazine, (Me3Si)2 TsN2H to form tosylhydrazides, EXn-1 (Me3Si)TsN2H, which on heating in vacuum, form a variety of azanes, hydrozones, diazenes and phophazanes. Ditosyltetrazene intermediate formed by dimerisation decomposes into ditosylhydrazine wi th liberation of nitrogen gas. |
| Page(s): | 2113-2119 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.43A(10) [October 2004] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 43A(10) 2113-2119.pdf | 1.07 MB | Adobe PDF | View/Open |
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