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http://nopr.niscpr.res.in/handle/123456789/20466| Title: | Molar volume and viscosity of cupric chloride in aqueous mannitol |
| Authors: | Kant, Shashi Dogra, Pankaj Kumar, Sushil |
| Issue Date: | Dec-2004 |
| Publisher: | NISCAIR-CSIR, India |
| IPC Code: | Int Cl.7 G01N |
| Abstract: | The apparent molar volume, (ϕv) and viscosity of cupric chloride have been determined in 2, 4 and 6 wt/wt percent aqueous mannitol solutions at 303, 308, 313 and 318K. The ϕv values vary linearly with square root of concentration of cupric chloride. The limiting apparent molar volume has been interpreted in terms of solute-solvent interaction. The ϕv0 values vary with temperature and can be represented in the power series of temperature. Structure making/breaking capacity of electrolyte is inferred from the sign of (∂2 ϕv0/∂T2 and dB/dT values. The apparent molar expansibility has also been determined. Cupric chloride has been found to be structure- maker in aqueous mannitol from molar volume as well as viscosity studies. |
| Page(s): | 2555-2557 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.43A(12) [December 2004] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 43A(12) 2555-2557.pdf | 643.86 kB | Adobe PDF | View/Open |
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