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http://nopr.niscpr.res.in/handle/123456789/20471| Title: | Synthesis and characterization of tridentate Schiff's base derived from 5-(2'-thiazolylazo) salicylaldehyde and p-methoxy aniline and their Mn(II), Co(II), Ni(II), Cu(n), Zn(II), Cd(II) and Hg(II) complexes |
| Authors: | Hankare, P P Gavali, LV Bhusea, V M Delekar, S D Rokade, R S |
| Issue Date: | Dec-2004 |
| Publisher: | NISCAIR-CSIR, India |
| IPC Code: | Int. Cl.7 C07F 15/06 C07F 15/04; C07F 1/08; C07F 3/06; C07F 3/08; C07F 3/10; C07F13/00; C07C 251/02 |
| Abstract: | A series of new complexes involving Mn(II), Co(II), Ni(II),Cu(II), 2n(II), Cd(II) and Hg(II) ions and Schiffs base ligand obtained by condensation of 5-(2'-thiazolylazo) salicylaldehyde and p-methoxy aniline have been synthesized. The complexes are characterized by elemental analysis, magnetic susceptibility, molar conductance, IR, electronic spectra, ESR and thermal analysis (TGA). The ONN environment of the metal ion is realized in the complexes by involvement of the -N=N- group in coordination. The analysis of magnetic moment and electronic spectral data indicate tetrahedral geometry for the Mn(II), Co(II), Ni(II), Zn(II), Cd(II) and Hg(II) complexes, while distorted tetrahedral geometry for the Cu(II) complex. |
| Page(s): | 2578-2581 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.43A(12) [December 2004] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 43A(12) 2578-2581.pdf | 998.6 kB | Adobe PDF | View/Open |
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