Please use this identifier to cite or link to this item: http://nopr.niscpr.res.in/handle/123456789/20587
Title: Studies on the reactions of lanthanide trichloride isopropanol complex, LnCl3.3PriOH, with Nb(OPri)5 or Al(OPri)3
Authors: Mishra, Shashank
Singh, Anirudh
Issue Date: Feb-2003
Publisher: NISCAIR-CSIR, India
Abstract: Reactions of LnCl3.3PriOH (Ln = Y, La, Pr, Nd, Sm, Gd, Er) with three equivalents of Nb(OPri)5, or freshly distilled Al(OPri)3 yield quantitatively derivatives of composition Ln { Nb(OPri)5Cl}3 or Ln{Al(OPri)3Cl}3, respectively. All these novel derivatives have been characterized by elemental analysis and spectroscopic (IR, 1H, 13C and 27Al NMR) studies. Molecular weight measurements have also been carried out on niobium derivatives.
Page(s): 305-308
ISSN: 0975-0975(Online); 0376-4710(Print)
Appears in Collections:IJC-A Vol.42A(02) [February 2003]

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