Please use this identifier to cite or link to this item:
http://nopr.niscpr.res.in/handle/123456789/20600| Title: | Synthesis, characterization, and spectroscopic properties of heterobimetallic , isopropoxides of Co, Ni and Cu containing diethanolaminate moiety |
| Authors: | Sharma, Kanupriya Sharma, Malti Singh, Anirudh Mehrotra, Ram C |
| Issue Date: | Mar-2003 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | Hydrocarbon-insoluble derivatives of the type M(deaH)2 (M = Co, Ni, Cu(II); deaH2 = diethanolamine) on reactions with Al(OPri)3 in 1:2 molar ratio yield hydrocarbon-soluble, monomeric heterobimetallic derivatives [{Al(OPri)2}2M(dea)2]· A different type of soluble heteroleptic derivatives has been prepared by the reactions of M{Al(OPri)4}2 with deaH2 in 1:1, 1:2 and 1:3 molar ratios. The reaction of M{Al(OPri)4}2 with four equivalents of diethanolamine yields a benzene insoluble product of composition M {Al(dea}2}2. All these new derivatives have been characterized by elemental analyses, molecular weight measurements and spectroscopic (Electronic and IR) studies. |
| Page(s): | 493-498 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.42A(03) [March 2003] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 42A(3) 493-498.pdf | 1.03 MB | Adobe PDF | View/Open |
Items in NOPR are protected by copyright, with all rights reserved, unless otherwise indicated.