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| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Ali, Mahammad | - |
| dc.contributor.author | Dutta, Amitava | - |
| dc.contributor.author | Gangopadhyay, Sumana | - |
| dc.date.accessioned | 2013-08-20T04:56:18Z | - |
| dc.date.available | 2013-08-20T04:56:18Z | - |
| dc.date.issued | 2003-03 | - |
| dc.identifier.issn | 0975-0975(Online); 0376-4710(Print) | - |
| dc.identifier.uri | http://hdl.handle.net/123456789/20608 | - |
| dc.description | 531-533 | en_US |
| dc.description.abstract | Kinetics of redox reaction between Iˉ and [MnIII(cdta)]ˉ has been investigated in aqueous solution by a stopped-flow technique at pH 3.26 (acetate buffer) and at 30, 35 40 and 45°C. The overall reaction is third order-first order in [MnIII(cdta)ˉ] and second order in [Iˉ]. Though no direct evidence has been obtained, an inner-sphere mechanism has been proposed based on the lability of the complex and is supported by the large negative value of ΔS# (-168 ± 6) JK-1 mol-1. | en_US |
| dc.language.iso | en_US | en_US |
| dc.publisher | NISCAIR-CSIR, India | en_US |
| dc.rights | CC Attribution-Noncommercial-No Derivative Works 2.5 India | en_US |
| dc.source | IJC-A Vol.42A(03) [March 2003] | en_US |
| dc.title | Kinetics of oxidation of iodide ion by trans-(cyclohexane-l ,2-diamine N,N,N',N' tetraacetato)manganate(III) weakly acidic solution | en_US |
| dc.type | Article | en_US |
| Appears in Collections: | IJC-A Vol.42A(03) [March 2003] | |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 42A(3) 531-533.pdf | 581.1 kB | Adobe PDF | View/Open |
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