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dc.contributor.authorAli, Mahammad-
dc.contributor.authorDutta, Amitava-
dc.contributor.authorGangopadhyay, Sumana-
dc.date.accessioned2013-08-20T04:56:18Z-
dc.date.available2013-08-20T04:56:18Z-
dc.date.issued2003-03-
dc.identifier.issn0975-0975(Online); 0376-4710(Print)-
dc.identifier.urihttp://hdl.handle.net/123456789/20608-
dc.description531-533en_US
dc.description.abstractKinetics of redox reaction between Iˉ and [MnIII(cdta)]ˉ has been investigated in aqueous solution by a stopped-flow technique at pH 3.26 (acetate buffer) and at 30, 35 40 and 45°C. The overall reaction is third order-first order in [MnIII(cdta)ˉ] and second order in [Iˉ]. Though no direct evidence has been obtained, an inner-sphere mechanism has been proposed based on the lability of the complex and is supported by the large negative value of ΔS# (-168 ± 6) JK-1 mol-1.en_US
dc.language.isoen_USen_US
dc.publisherNISCAIR-CSIR, Indiaen_US
dc.rights CC Attribution-Noncommercial-No Derivative Works 2.5 Indiaen_US
dc.sourceIJC-A Vol.42A(03) [March 2003]en_US
dc.titleKinetics of oxidation of iodide ion by trans-(cyclohexane-l ,2-diamine N,N,N',N' tetraacetato)manganate(III) weakly acidic solutionen_US
dc.typeArticleen_US
Appears in Collections:IJC-A Vol.42A(03) [March 2003]

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