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http://nopr.niscpr.res.in/handle/123456789/20614| Title: | Synthesis, structural characterization and thermal behaviour of bis(l-phenyl-l ,3 - butanedionato) non-oxovanadium(IV) aryloxides |
| Authors: | Sharma, Neeraj Ritu Kaistha, Atul Bhatt, Sarvjeet S Chaudhry, Subhash C |
| Issue Date: | Mar-2003 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | The non-oxovanadium(IV) aryloxides of composition [VCl(bzac)2(OAr)1,2] {where OArl= -OC6H4But-4 and OAr2= -OC6H4OMe-4; bzac= 1-phenyl-1,3-butane-dionato ion (C6H5COCHCOCH3)-} have been synthesized by the direct reaction of VCl2(bzac)2 with 4-tert-butyl and 4-methoxy phenols in CCl4 while [V(bzac)2(OAr)21,2] have been prepared from VCl2(bzac)2 and trimethylsilyl derivatives of these phenols. The complexes have been characterized by elemental analyses, molar conductance, molecular mass determinations, FT- infrared, UV-vis, ESR spectroscopy and magnetic susceptibility measurements. Thermal behaviour of the complexes is consistent with the proposed formulations. |
| Page(s): | 555-558 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.42A(03) [March 2003] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 42A(3) 555-558.pdf | 915.85 kB | Adobe PDF | View/Open |
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