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http://nopr.niscpr.res.in/handle/123456789/20703Full metadata record
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Chattopadhyay, Nitin | - |
| dc.contributor.author | Serpa, Carlos | - |
| dc.contributor.author | Arnaut, Luis G | - |
| dc.contributor.author | Formosinho, Sebastiao J | - |
| dc.date.accessioned | 2013-08-21T05:41:11Z | - |
| dc.date.available | 2013-08-21T05:41:11Z | - |
| dc.date.issued | 2003-08 | - |
| dc.identifier.issn | 0975-0975(Online); 0376-4710(Print) | - |
| dc.identifier.uri | http://hdl.handle.net/123456789/20703 | - |
| dc.description | 1827-1832 | en_US |
| dc.description.abstract | Energetics of formation of the intermediate during the photocyclisation of phenylbenzoquinone (PBQ) to 2-hydroxydibenzofuran (HDBF) in methanol solvent has been investigated by employing the time-resolved photoacoustic calorimetric (TRPAC) technique. The study, in conjugation with the nanosecond/microsecond flash photolytic observations, confirms the formation of a long lived intermediate during the photocyclisation reaction. TRPAC result and semi-empirical (AM1 and PM3) calculations suggest that the intermediate is a biradical. | en_US |
| dc.language.iso | en_US | en_US |
| dc.publisher | NISCAIR-CSIR, India | en_US |
| dc.rights |  CC Attribution-Noncommercial-No Derivative Works 2.5 India | en_US |
| dc.source | IJC-A Vol.42A(08) [August 2003] | en_US |
| dc.title | Photocyclisation of phenylbenzoquinone: A time resolved photoacoustic calorimetric and flash photolytic study | en_US |
| dc.type | Article | en_US |
| Appears in Collections: | IJC-A Vol.42A(08) [August 2003] | |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 42A(8) 1827-1832.pdf | 1.33 MB | Adobe PDF | View/Open |
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