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http://nopr.niscpr.res.in/handle/123456789/20840| Title: | Synthesis and spectroscopic studies on platinum(II) complexes of thiosemicarbazone derivatives of p-anisaldehyde, p-tolualdehyde and p-vanillin |
| Authors: | Akinchan, Narayan T Akinchan, Richa |
| Issue Date: | Jun-2002 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | The platinum(II) complexes of thiosemicarbazone derivatives of p-anisaldehyde (ATSCH), p-tolualdehyde (TTSCH) and p-vanillin (VTSCH) have been prepared and characterized by analytical, molar conductance, infrared, electronic, 1H and 13C NMR spectral data. Thiosemicarbazones exist in thione form and coordinate through thiolato/thione sulphur and azomethine nitrogen. The chloro bridged dinuclear structures for [Pt(ATSC)Cl]2 [Pt(TTSC)Cl]2 and [Pt(VTSC)Cl]2 having four coordinate platinum(II) centres and square planar for [Pt(ATSCH)2]Cl2, [Pt(TTSCH)2]Cl2 and (Pt(VTSCH)2Cl2 are suggested. |
| Page(s): | 1152-1156 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.41A(06) [June 2002] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 41A(6) 1152-1156.pdf | 1.17 MB | Adobe PDF | View/Open |
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