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http://nopr.niscpr.res.in/handle/123456789/20861| Title: | Silyl-nitrogen compounds: Part XIII-Reactions of metal halides with silylated tosylhydrazines |
| Authors: | Vasisht, S K Venugopalan, P Kataria, Jyoti Sharma, Anuradha |
| Issue Date: | Oct-2002 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | Bis(trimethylsilyl)tosylhydrazine (Me3Si)2TsN2H reacts with ECln (E=Al,Sn,Sb or Ti) to liberate Me3SiCl and in the process form tosylhydrazides, ECln-1(Me3Si)TsN2H. These compounds decompose on heating in vacuo to form a variety of azane derivatives with the loss of volatile products like Me3SiCl, HCl or SbCl3. Ditosyltetrazene intermediate decomposes into ditosylhydrazine whose structure is determined by X-ray diffraction. |
| Page(s): | 2054-2059 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.41A(10) [October 2002] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 41A(10) 2054-2059.pdf | 1.16 MB | Adobe PDF | View/Open |
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