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http://nopr.niscpr.res.in/handle/123456789/20866| Title: | Synthesis and characterization of dinuclear ruthenium(II) and ruthenium(III) acetylacetonato complexes with dianion of 2,5-dihydroxy-1,4-benzoquinone as bridging ligand |
| Authors: | Gupta, Akhilesh K Gupta, Anupama Choudhury, Anuradha |
| Issue Date: | Oct-2002 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | Synthesis of [{(acac)2Ru}2(μ-L)] and [{(bipy)(acac)Ru}2(μ-L)] (where acac=acetylacetonato, bipy=2,2'-bipyridine) has been achieved by the reaction of K2L (where K2L=dipotassium salt of 2,5-dihydroxy-1,4-benzoquinone) with two equivalents of cis-[RuIII(acac)2(CH3CN)2] or [RuIIBr(acac)(bipy)]. The complexes have been characterized on the basis of elemental analyses, magnetic susceptibility and conductivity data, IR, UV-visible and 1H NMR spectral data and cyclic voltammetric studies. |
| Page(s): | 2076-2078 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.41A(10) [October 2002] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 41A(10) 2076-2078.pdf | 858.22 kB | Adobe PDF | View/Open |
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