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http://nopr.niscpr.res.in/handle/123456789/21061| Title: | Synthesis and characterization of some novel mixed-ligand cyanonitrosyl {MnNO}6 complexes of manganese(I) involving multifunctional bioactive organic donors |
| Authors: | Maurya, R C Batalia, S |
| Issue Date: | Jun-2001 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | Novel mixed-ligand cyanonitrosyl complexes of manganese(I), formed by interaction of pentacyanoni trosylmanganate(I) anion,[Mn(NO)(CN)]3- with 2,3-pyridincdiearboxylic acid (PDA), 7 -chloro-4-(3-diethylaminomethyl-4-hydroxyanilino)quinoline dihydrochloride dihydrate (CDAHQ) and 4,4'-diaminodiphenyl sulphone (DADPS), have been synthesized and characterized by elemental analyses, molar conductances, magnetic and decomposition temperature measurements, infrared and electronic spectral studies. The complexes have the compositions, [Mn(NO)(CN)2(PDA)2(H2O)],Mn(NO)(CN)2 (CDAHQ) (H2O)2] and Mn(NO)(CN)2 (DADPS)(H2O)]2.Suitable octahedral structures have been proposed for these complexes. |
| Page(s): | 652-655 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.40A(06) [June 2001] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 40A(6) 652-655.pdf | 850.87 kB | Adobe PDF | View/Open |
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