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http://nopr.niscpr.res.in/handle/123456789/21103| Title: | Synthesis and characterization of Ru(II) arene complexes, [Ru(η6-arene)(dppm)H]+ (η6-arene=benzene, p-cymene or hexamethylbenzene), [Ru(η6-arene)(py)3]2+ and [Ru(η6-arene)(py)2Cl]+ |
| Authors: | Sisodiya, O S Sahay, AN Pandey, D S |
| Issue Date: | Apr-2000 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | Reactions of [{Ru(η6-arene)Cl2}2] (η6-arene = benzene, p-cymene, hexamethylbenzene) in methanol, in presence of AgBF4/AgPF6 with 1,2-bis(diphenylphosphino)methane (dppm) give cationic hydrido complexes [Ru(η6-arene)(dppm)H]+.However, under similar and some changed conditions, reaction with pyridine result in the formation of [Ru(η6-arene)(py)3]2+ and [Ru(η6-arene)(py)2Cl]+. The reaction products have been characterized by elemental analyses, IR, 1H, 31P NMR and FAB mass spectra. |
| Page(s): | 453-456 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.39A(04) [April 2000] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 39A(4) 453-456.pdf | 799.09 kB | Adobe PDF | View/Open |
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