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http://nopr.niscpr.res.in/handle/123456789/21156| Title: | Synthesis, characterisation and absorption spectroscopy of mono and dinuclear complexes of platinum(II) and palladium(II) |
| Authors: | Anbalagan, V Srivastava, T S |
| Issue Date: | Jun-2000 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | Two mononuclear complexes of the formula [M(bpy)(dhb)] and two dinuclear complexes of the formula [(M(bpy))2(thb)] {where M=Pd(II) or Pt(II), bpy is 2,2' -bipyridine, dhb is the dianion of 3,4-dihydroxybenzaldehyde and thb is the tetraanion of 3,3',4,4'-tetrahydroxybenzaldazine} have been prepared and characterized by chemical analysis, IR and proton NMR spectroscopy. These complexes are found to show a low lying, solvent-dependent, ligand-to-ligand charge-transfer (LLCT) band. A comparison on the spectroscopic behaviour of mononuclear and dinuclear complexes is made. |
| Page(s): | 667-671 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.39A(06) [June 2000] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 39A(6) 667-671.pdf | 1.33 MB | Adobe PDF | View/Open |
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