Please use this identifier to cite or link to this item:
http://nopr.niscpr.res.in/handle/123456789/21192| Title: | Molybdenum(V) complexes of dithiocarbonates derived from glucose, sucrose and triphenylmethylcarbinol |
| Authors: | Mohandoss, K Nagaraja, K S |
| Issue Date: | Oct-2000 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | -Glucose,
sucrose and triphenylmethylcarbinol dithiocarbonate complexes of molybdenum(V),
[Mo2OS3(glu -2CS2)).2H2O, [Mo2S4(suc-4CS2)].2H2O,
and [Mo2OS3(Ph3COCS2)2].2H2O,
respectively have been synthesized. The compositions are strongly influenced by
the nature of xanthates and the experimental conditions of preparation. The TG-DTA
data suggest the presence of lattice water. On the basis of magnetic moment and
spectroscopic data, oxo or sulphido bridged structures are suggested for the molybdenum
compounds. |
| Page(s): | 1083-1086 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.39A(10) [October 2000] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 39A(10) 1083-1086.pdf | 820.12 kB | Adobe PDF | View/Open |
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-Glucose,
sucrose and triphenylmethylcarbinol dithiocarbonate complexes of molybdenum(V),
[Mo2OS3(glu -2CS2)).2H2O, [Mo2S4(suc-4CS2)].2H2O,
and [Mo2OS3(Ph3COCS2)2].2H2O,
respectively have been synthesized. The compositions are strongly influenced by
the nature of xanthates and the experimental conditions of preparation. The TG-DTA
data suggest the presence of lattice water. On the basis of magnetic moment and
spectroscopic data, oxo or sulphido bridged structures are suggested for the molybdenum
compounds.