Please use this identifier to cite or link to this item: http://nopr.niscpr.res.in/handle/123456789/21200
Title: Ion-exchange properties of 8-hydroxyquinoline-biuret-formaldehyde tercopolymers
Authors: Gurnule, Wasudeo B
Juneja, H D
Paliwal, L J
Issue Date: Oct-2000
Publisher: NISCAIR-CSIR, India
Abstract: Tercopolymer (8-HQBF) prepared by condensation of 8-hydroxyquinoline (8-HQ) and biuret (B) with formaldehyde (F) in the presence of 2M HCl as catalyst was proved to be a selective chelating ion-exchange tercopolymer for certain metals. Chelating ion-exchange properties of this tercopolymers are studied for Fe3+, Cu2+, Ni2+, Co2+, Zn2+, Cd2+ and Pb2+ ions. A batch equilibrium method has been employed in the study of the selectivity of metal ion uptake involving the measurements of the distribution of a given metal ion between the polymer sample and a solution containing the metal ion. The study has been carried out over a wide pH range and in media of various ionic strengths. The polymer shows a higher selectivity for Fe3+, Cu2+ and Ni2+ ions than for Co2+, Zn2+, Cd2+ and Pb2+ ions.
Page(s): 1110-1113
ISSN: 0975-0975(Online); 0376-4710(Print)
Appears in Collections:IJC-A Vol.39A(10) [October 2000]

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