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| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Shukla, Pragya | - |
| dc.contributor.author | Upadhyay, Santosh K | - |
| dc.date.accessioned | 2008-09-30T09:35:33Z | - |
| dc.date.available | 2008-09-30T09:35:33Z | - |
| dc.date.issued | 2008-07 | - |
| dc.identifier.issn | 0376-4710 | - |
| dc.identifier.uri | http://hdl.handle.net/123456789/2124 | - |
| dc.description | 1037-1040 | en_US |
| dc.description.abstract | The kinetics of oxidation of non-ionic surfactants, viz. polyoxyethylene(10)octylphenol (Triton X-100) and polyoxyethyleneglycol dodecylether (Brij-35) by potassium permangnate in aqueous H₂SO₄ medium have been investigated in temperature range 35-45C. The reactions show first order dependence of rate with respect to [MnO₄⁻]. The order of reaction in surfactant and H₂SO₄ decreases from unity at higher [surfactant] and [H₂SO₄], respectively. Probable reaction mechanism involving an intermediate between surfactant and active species of the oxidant is proposed and constants involved in the rate law have been evaluated. | en_US |
| dc.language.iso | en_US | en_US |
| dc.publisher | CSIR | en_US |
| dc.relation.ispartofseries | Int. Cl. ⁸ C07B33/00 | en_US |
| dc.source | IJCA Vol.47A(7) [July 2008] | en_US |
| dc.title | Kinetics of oxidation of non-ionic surfactants (Triton X-100 and Brij-35) by KMnO₄ in H₂SO₄ medium | en_US |
| dc.type | Article | en_US |
| Appears in Collections: | IJC-A Vol.47A(07) [July 2008] | |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 47A(7) 1037-1040.pdf | 114.86 kB | Adobe PDF | View/Open |
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