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http://nopr.niscpr.res.in/handle/123456789/21635| Title: | A convenient enantiospecific methodology for (-)-(1R,5S)-1 ,5-dimethylbicyclo[3.3.0]octa-2,7-dione: A formal total synthesis of (-)-ceratopicanol |
| Authors: | Srikrishna, A Babu, N Chandrasekhar Dethe, Dattatraya H |
| Issue Date: | Jul-2003 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | An enantiospecific formal total synthesis of (-)-ceratopicanol starting from the readily and abundantly available monoterpene (R)-limonene is described. A combination of Claisen rearrangement- intramolecular diazo ketone cyclopropanation-regiospecific reductive cyclopropane cleavage reactions are employed for the stereo- and regiospecific generation of the two vicinal ring junction quaternary carbon atoms. |
| Page(s): | 1688-1690 |
| ISSN: | 0975-0983(Online); 0376-4699(Print) |
| Appears in Collections: | IJC-B Vol.42B(07) [July 2003] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCB 42B(7) 1688-1690.pdf | 695.83 kB | Adobe PDF | View/Open |
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