Please use this identifier to cite or link to this item:
http://nopr.niscpr.res.in/handle/123456789/21798| Title: | Mechanistic investigation of asymmetric aminohydroxylation of alkenes† |
| Authors: | Lohray, B B Bhushan, Vidya Reddy, G Jaipal Reddy, A Sekar |
| Issue Date: | Jan-2002 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | Transfer of nitrogen and oxygen in asymmetric aminohydroxylation (AA) has been examined. Electronic as well as steric effect on the nature of oxidizing agent and nitrogen source affect chemo, regio and stereoselectivity in AA reaction. A three cycle mechanistic pathway has been proposed. Results have been rationalized through an addition of alkene to Os=N bond in a [2+2] cycloaddition manner. |
| Page(s): | 161-168 |
| ISSN: | 0975-0983(Online); 0376-4699(Print) |
| Appears in Collections: | IJC-B Vol.41B(01) [January 2002] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCB 41B(1) 161-168.pdf | 1.76 MB | Adobe PDF | View/Open |
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