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http://nopr.niscpr.res.in/handle/123456789/22238Full metadata record
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Nallu, M | - |
| dc.contributor.author | Sathiskumar, V | - |
| dc.contributor.author | Sangeetha, M K | - |
| dc.contributor.author | Sarkunam, K | - |
| dc.date.accessioned | 2013-10-18T06:09:45Z | - |
| dc.date.available | 2013-10-18T06:09:45Z | - |
| dc.date.issued | 2001-04 | - |
| dc.identifier.issn | 0975-0983(Online); 0376-4699(Print) | - |
| dc.identifier.uri | http://hdl.handle.net/123456789/22238 | - |
| dc.description | 295-298 | en_US |
| dc.description.abstract | Active halide containing electron withdrawing group (EWG) α-to halogen readily reacts with 4-dimethylaminopyridine (DMAP) to give stable salt of pyridinium halide (1-6). The reaction between 1-phenacyl-4-dimethylaminopyridinium halide(s) (1 and 2) and aq. NaOH instantaneously generates 4-dimethylaminopyridinium-1-(2'-hydroxy-2'-phenyl)vinylide 7 as brownish yellow stable crystalline solid which is reported for the first time. Whereas, the other compounds 3-6 do not generate such type of ylide under identical experimental conditions. | en_US |
| dc.language.iso | en_US | en_US |
| dc.publisher | NISCAIR-CSIR, India | en_US |
| dc.rights |  CC Attribution-Noncommercial-No Derivative Works 2.5 India | en_US |
| dc.source | IJC-B Vol.40B(04) [April 2001] | en_US |
| dc.title | 1-Phenacyl-, 1-carbethoxymethyl- and 1-benzyl-4-dimethylaminopyridinium halides: Isolation and use for generating ylide | en_US |
| dc.type | Article | en_US |
| Appears in Collections: | IJC-B Vol.40B(04) [April 2001] | |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCB 40B(4) 295-298.pdf | 802.91 kB | Adobe PDF | View/Open |
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