Please use this identifier to cite or link to this item: http://nopr.niscpr.res.in/handle/123456789/22930
Title: Catalytic esterification of benzyl alcohol with acetic acid by zeolites and their modified forms
Authors: Sharath, K R
Vijayashree, Sreenivasan
Nagaraju, N
Issue Date: Sep-2001
Publisher: NISCAIR-CSIR, India
Abstract: An attempt has been made to synthesise benzyl acetate from benzyl alcohol and acetic acid using Na-β, Na-Y, and NaZSM5 zeolites and their ion exchanged forms as catalysts. All the catalysts are characterised for their surface acidity, surface area and crystallinity by n-butyl amine titration method, BET and XRD respectively. The esterification reaction has been carried out in liquid phase taking the reactants in different acid to alcohol molar ratios (1:1, 1:2, 2:1). The amount of the ester formed has been estimated indirectly by titrating the unreacted acid with a standard base. The selectivity was found to be 100% with reasonably good yield (44-83%). The catalysts are also checked for their reusability.
Page(s): 362-367
ISSN: 0975-0991 (Online); 0971-457X (Print)
Appears in Collections:IJCT Vol.08(5) [September 2001]

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