<span style="font-size:14.0pt;line-height: 115%;font-family:"Times New Roman";mso-fareast-font-family:"Times New Roman"; color:black;mso-ansi-language:EN-IN;mso-fareast-language:EN-IN;mso-bidi-language: HI" lang="EN-IN">Synthesis of disperse dyes based on 5-hydroxyquinolino-[2,1<i>-b </i>]-quinazolin-12(<i>H</i>)one system and their dyeing performance on polyester fibre</span>

Abstract

<span style="font-size:14.0pt;line-height: 115%;font-family:" times="" new="" roman";mso-fareast-font-family:"times="" roman";="" color:black;mso-ansi-language:en-in;mso-fareast-language:en-in;mso-bidi-language:="" hi"="" lang="EN-IN">Twenty 6-arylazo-5-hydroxyquinolino-[2 ,1-<i>b</i>]-quinazolin-12(<i>H</i>)-ones (<b>V_a-t</b>) were prepared by coupling 5-hydroxyquinolino[2,1-<i>b</i>]-quinazolin-12(<i>H</i>)-one (<b>III</b>) with various diazo components (<b>IV_a-t</b>) . The compound <b>III </b>was prepared by the condensation of 2-methyl-1 ,3-benzoxazin -8-one (<b>I</b>) with anthranilic acid, giving initially 2-methyl-3-[l-carboxyphenyl]-4-oxoquinazoline (<b>II</b>) followed by the ring closure. The compounds <b>V_a-t</b>were characterized by element al and spectral analyses and their dyeing performance on polyester fibre was assessed. These compounds, when applied on polyester fibres, gave orange, brown and yellow shades with poor to good light fastness, very good to excellent wash fastness and poor to excellent exhaustion .</span>