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http://nopr.niscpr.res.in/handle/123456789/26056| Title: | Evidence for direct hydride ion transfer from phosphorus to manganese(VII) in the permanganate oxidation of hypophosphite ion |
| Authors: | Sharma, Kamla Mehrotra, Raj N Jr., G P Haight |
| Issue Date: | Jul-2000 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | The reaction between permanganate ion and hypophosphorous acid, P(I), in acid perchlorate medium exhibits P(I)/MnO4-stoichiometry of 2:1 , and is first order in MnO4- and an order < 1 in [H3PO2] . Kinetic studies revealed inhibition of reaction at high [H2PO2-]. . . |
| Page(s): | 709-720 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.39A(07) [July 2000] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 39A(7) 709-720.pdf | 4.64 MB | Adobe PDF | View/Open |
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