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http://nopr.niscpr.res.in/handle/123456789/26090| Title: | [K(18C6)]2[Pt(SCN)4](H2O): A novel one-dimensional coordination polymer with K-N bonds |
| Authors: | Liu, Ying Dou, Jianmin Zhuh, Lanying Sun, Dezhi Zheng, Peiju |
| Issue Date: | Sep-2000 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | Pt (II) 18-crown-6 complex [K(18C6)]2[Pt(SCN)4](H2O) has been isolated and characterized by X-ray diffraction analysis. The crystal structure belongs to monoclinic, space group P21/ n with cell dimensions, a = 1.1116(1), b = 1.2258(1), c = 1.5856(1) nm, β = 93.479(9)o , V = 2.1567(3) nm3, Z = 2, R = 0.033 and Rw = 0.051 . In the solid state, the complex displays a one-dimensional infinite chain of two [K(18C6)]+ complex cations and a [Pt (SCN)4]2- anion bridged by one H2O molecule between adjacent [K(18C6)]+ units. |
| Page(s): | 983-984 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.39A(09) [September 2000] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 39A(9) 983-984.pdf | 443.9 kB | Adobe PDF | View/Open |
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