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http://nopr.niscpr.res.in/handle/123456789/26091| Title: | Synthesis and structure of the copper(I) complex- [Cu(dppm) (2,2'-bipy)]2(NO3)2 |
| Authors: | Dongmei, Wang Ruina, Yang Yimin, Hou Xiaoyuan, Hu Douman, Jin |
| Issue Date: | Sep-2000 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | Binuclear copper(I) complex [Cu(dppm) (2,2'-bipy)]2(NO3)2 ,(1) dppm=Ph2PCH2PPh2] has been synthesized by a ligand replacement reaction. X-ray crystal structure of the complex (1) shows that dppm coordinates as a bridging bidentate ligand, and 2,2 -bipy as a bidentate ligand to the Cu(I) atoms with tetrahedral structure. NO3- behaves as a free ion in this newly prepared binuclear copper(I) complex. Crystals (1) are monoclinic P21/n, a = 1.4663(5); b = 1.3076(5), c = 1.9910(6) nm; β =110.66(3)o, V = 3.5719 nm3, Z = 2, F(000) = 1536, Dc= 1.332 g cm-3, R= 0.06320, Rw = 0.08132. |
| Page(s): | 985-988 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.39A(09) [September 2000] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 39A(9) 985-988.pdf | 867.88 kB | Adobe PDF | View/Open |
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