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http://nopr.niscpr.res.in/handle/123456789/30689| Title: | An efficient and chemoselective method for conversion of carbonyl compounds to 1,3-oxathiolanes with 2-mercaptoethanol catalyzed by TiCl4-montmorillonitc |
| Authors: | Jin, Tong-Shou Zhao, Rui-Qiao Ma, Yen-Ran Yang, Mi-Na Guo, Jun-Jic Li, Tong-Shuang |
| Keywords: | 1,3-oxathiolanes;Aldehydes;Ketones;Chemoselective;2-mercaptoethanol;Conversion |
| Issue Date: | Feb-2006 |
| Publisher: | NISCAIR-CSIR, India |
| IPC Code: | Int.CI.7 C 07 D |
| Abstract: | Formation of 1,3-oxathiolanes from aldehydes and ketones using 2-mercaptoethanol in the presence of TiCl4-montmorillonite under mild reaction conditions in excellent yields is described. Chernoselective monothioacetalization of aldehyde in the presence of ketone can also he achieved in high yield. |
| Page(s): | 503-505 |
| ISSN: | 0975-0983(Online); 0376-4699(Print) |
| Appears in Collections: | IJC-B Vol.45B(02) [February 2006] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCB 45B(2) 503-505.pdf | 585.23 kB | Adobe PDF | View/Open |
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