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| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Srikrishna, A | - |
| dc.contributor.author | Ramachary, D B | - |
| dc.date.accessioned | 2015-02-27T04:44:20Z | - |
| dc.date.available | 2015-02-27T04:44:20Z | - |
| dc.date.issued | 2006-05 | - |
| dc.identifier.issn | 0975-0983(Online); 0376-4699(Print) | - |
| dc.identifier.uri | http://hdl.handle.net/123456789/30695 | - |
| dc.description | 1216-1226 | en_US |
| dc.description.abstract | Total synthesis of (±)-grimaldone, epigrimaldone and α-cuparenone has been described. A combination of orthoester Claisen rearrangement, an acid catalysed rearrangement of a diazoketone for the generation of bicyclo[4.2.1]nonanedione, a retro-Claisen condensation and an intramolecular diazoketone cyciopropanation reaction have been employed for the construction of three contiguous quaternary atoms present in grimaldone and epigrimaldones. | en_US |
| dc.language.iso | en_US | en_US |
| dc.publisher | NISCAIR-CSIR, India | en_US |
| dc.relation.ispartofseries | Int.Cl.8 C 07 C | en_US |
| dc.rights |  CC Attribution-Noncommercial-No Derivative Works 2.5 India | en_US |
| dc.source | IJC-B Vol.45B(05) [May 2006] | en_US |
| dc.subject | Grimaldone | en_US |
| dc.subject | Epigrimaldone | en_US |
| dc.subject | α-cuparenone | en_US |
| dc.subject | Claisen rearrangement | en_US |
| dc.subject | Diazoketone | en_US |
| dc.subject | Cyclopropanation reaction | en_US |
| dc.subject | Retro-Claisen condensation | en_US |
| dc.title | Total synthesis of (±)-grimaldone, epigrimaldone and α-cuparenones | en_US |
| dc.type | Article | en_US |
| Appears in Collections: | IJC-B Vol.45B(05) [May 2006] | |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCB 45B(5) 1216-1226.pdf | 2.7 MB | Adobe PDF | View/Open |
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