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http://nopr.niscpr.res.in/handle/123456789/33771| Title: | Tetraaquabis(4-methoxyphenylacetato-O') magnesium(II) dihydrate and catena-poly[[(diaqua)manganese(II)]- bis(μ2-4-methoxyphenylacetato-O,O')]: A monomeric and a two-dimensional coordination polymer based on 4-methoxyphenylacetic acid |
| Authors: | Dhavskar, Kiran T Srinivasan, Bikshandarkoil R |
| Keywords: | Coordination polymer;Two-dimensional coordination polymers;Monodentate ligands;Bridging bidentate ligands;Methoxyphenylacetic acid;Manganese;Magnesium |
| Issue Date: | 15-Feb-2016 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | The synthesis and characterization of tetraaquabis(4-methoxyphenylacetato-O')magnesium(II) dihydrate (1) and catena-poly[[(diaqua)manganese(II)]bis(μ2-4-methoxyphenylacetato-O,O')] (2) based on 4-methoxyphenylacetic acid (4-mpaH) ligand is reported. In 1, the unique 4-mpa functions as a monodentate ligand for Mg(II) situated on an inversion centre, resulting in a monomeric Mg(II) complex. The Mn(II) in 2 is also located on an inversion centre and the μ2-bridging bidentate coordination mode of the unique 4-mpa ligand results in the formation of a two-dimensional manganese coordination polymer. |
| Page(s): | 170-176 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.55A(02) [February 2016] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 55A(2) 170-176_Suppl Data.pdf | Supplementary Data | 505.24 kB | Adobe PDF | View/Open |
| IJCA 55A(2) 170-176.pdf | Main Article | 1.11 MB | Adobe PDF | View/Open |
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