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http://nopr.niscpr.res.in/handle/123456789/39873| Title: | Synthesis of isomaleonitrile dithiolato bridged heterobimetallic complexes, M[Pb(i-MNT)2], and their conductance behaviour |
| Authors: | Singh, Nanhai Prasad, Lal Bahadur |
| Issue Date: | Feb-1998 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | Heterobimetallic complexes of the type M[Pb(i-MNT)2l (M=Ni(lI), Co(ll), Zn(lI), Cd(lI), Cu(lI) and dioxouranium(VI); i-MNT = isomaleonitriledithiolate2- have been synthesized and characterized on the basis of elemental analysis, molar conductance,magnetic susceptibility, infrared and UV-visible spectral studies. Solid state electrical conductivity measurements suggest that the complexes behave as semiconductors. Their conductivities increase with the increase in temperature from 308 to 353 K. One of the compounds, Zn[Pb(i-MNT)2], shows a band gap (1.02 eV) which is quite worthy of further investigations. |
| Page(s): | 169-172 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.37A(02) [February 1998] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 37A(2) 169-172.pdf | 421.81 kB | Adobe PDF | View/Open |
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