Please use this identifier to cite or link to this item: http://nopr.niscpr.res.in/handle/123456789/39888
Title: Effect of ion-pairing on the kinetics of aquation of bromopentamminecobalt(lll) perchlorate in dicarboxylate-acetate media
Authors: Zaghloul, A A
EI-Shazly, Sh A
Khalil, M M
Amira, M F
Issue Date: Jan-1995
Publisher: NISCAIR-CSIR, India
Abstract: Kinetics of aquation of [Co(NH3)5Br]2+ in different types of dicarboxylate solutions containing acetone (10%, v/ v), at different temperatures have been investigated in the light of the. effects of ion-pairing on reaction rates and mechanism. A new empirical correlation between the rate coefficient and the stoichiometric concentration of the ion-pairing dicarboxylate ligand (C1); has been established and a reaction mechanism is proposed.
Page(s): 52-54
ISSN: 0975-0975(Online); 0376-4710(Print)
Appears in Collections:IJC-A Vol.34A(01) [January 1995]

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