Please use this identifier to cite or link to this item:
http://nopr.niscpr.res.in/handle/123456789/39927| Title: | Kinetics and mechanism of Pd(II) catalysed oxidation of some primary amines and aminoalcohols by alkaline hexacyanoferrate(lll) |
| Authors: | Shukla, Anju Upadhyay, Santosh K |
| Issue Date: | Feb-1995 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | The kinetics of oxidation of primary amines (n-butylamine and isopropylamine) and aminoalcohols (2-aminoethanol and 3-aminopropanol) by alkaline hexacyanoferrate(III) have been studied in the presence of PdCl2 as catalyst. The order of reaction in Fe(CN) is always unity while that in substrate decreases from unity at higher [substrate]. The rate is proportional to [Pd(ll)] and is independent to [OH-] (under the conditions when [OH-]> [PdCI2]). A mechanism involving {Pd(ll)-A} and {Pd(II)-(A)2} (where A represents amine or aminoalcohol) intermediate complexes is proposed. |
| Page(s): | 120-123 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.34A(02) [February 1995] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 34A(2) 120-123.pdf | 854.48 kB | Adobe PDF | View/Open |
Items in NOPR are protected by copyright, with all rights reserved, unless otherwise indicated.