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http://nopr.niscpr.res.in/handle/123456789/40072| Title: | Synthesis and characterization of nonaisopropoxodizirconatotin(IV) complexes |
| Authors: | Mathur, Sanjay Singh, Anirudh Mehrotra, Ram C |
| Issue Date: | Jun-1995 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | A number of novel heteroleptic nonaisopropoxodizirconatotin(IV) complexes of the type [Sn{Zr2(OPri)9}nCl4-n](where n= 1-3) have been synthesised by the reactions of SnCl4 with KZr2(OPri)9,in benzene in requisite (1:1, 1:2, or 1:3) molar ratios. Replacement of chloride in these derivatives by an appropriate alkoxide affords volatile, heterobimetallic derivatives of the type [Sn{Zr2(OPri )9}n(OR)4-n] (R =Pri, But, n = 2 or 3). These novel heterometal alkoxides have been characterized by elemental analyses, molecular weight measurements, IR and multinuclear (1H, 13C and 119Sn) NMR spectral studies. |
| Page(s): | 454-458 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.34A(06) [June 1995] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 34A(6) 454-458.pdf | 1.18 MB | Adobe PDF | View/Open |
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