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http://nopr.niscpr.res.in/handle/123456789/40147Full metadata record
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Ganesan, T K | - |
| dc.contributor.author | Bharathy, J R Bosco | - |
| dc.contributor.author | Sheriff, A I Md | - |
| dc.contributor.author | Rajagopal, S | - |
| dc.date.accessioned | 2017-02-07T05:55:35Z | - |
| dc.date.available | 2017-02-07T05:55:35Z | - |
| dc.date.issued | 1995-07 | - |
| dc.identifier.issn | 0975-0975(Online); 0376-4710(Print) | - |
| dc.identifier.uri | http://nopr.niscair.res.in/handle/123456789/40147 | - |
| dc.description | 522-528 | en_US |
| dc.description.abstract | Carboxylato-bound Cr(V) oxidation of aryl methyl sulphides (ArSMe) proceeds through a complex formation between the oxidant and substrate. The peculiar substituent effect observed is attributed to the reaction being carried out at a temperature close to the isokinetic temperature. Comparison of the kinetic results observed with-Cr(V) and Cr(VI) oxidations points out the operation of different mechanisms-single electron transfer in Cr(VI) oxidation and complex formation followed by ligand coupling in Cr(V) oxidation. | en_US |
| dc.language.iso | en_US | en_US |
| dc.publisher | NISCAIR-CSIR, India | en_US |
| dc.rights |  CC Attribution-Noncommercial-No Derivative Works 2.5 India | en_US |
| dc.source | IJC-A Vol.34A(07) [July 1995] | en_US |
| dc.title | Kinetics of oxidation of organic sulphides with carboxylato-bound Chromium(V) | en_US |
| dc.type | Article | en_US |
| Appears in Collections: | IJC-A Vol.34A(07) [July 1995] | |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 34A(7) 522-528.pdf | 1.88 MB | Adobe PDF | View/Open |
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