Please use this identifier to cite or link to this item: http://nopr.niscpr.res.in/handle/123456789/40160
Title: Synthesis and X-ray characterization of potassium-chloride-hexafiuorometallates
Authors: Müller, Horst
Abberger, S
Issue Date: Jul-1995
Publisher: NISCAIR-CSIR, India
Abstract: Potassium-chloride-hexafluororhenate, K3Cl[ReF6], has been prepared by dissolving KCl and K2ReF6 and then precipitating with cold HCl. It crystallises in analogy to (NH4)3[SiF6] and K3F[SiF6] in a tetragonal structure, with an anti-perovskite superstructure. The complex is converted into a cubic modification at 140°C. The complexes K3Cl[OsF6] and K3Cl[IrF6] have also been synthesised corresponding to the Re compound.
Page(s): 563-566
ISSN: 0975-0975(Online); 0376-4710(Print)
Appears in Collections:IJC-A Vol.34A(07) [July 1995]

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