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| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Dash, Anadi C | - |
| dc.contributor.author | Patnaik, Ajay K | - |
| dc.contributor.author | Das, Nigamananda | - |
| dc.date.accessioned | 2017-02-07T06:54:31Z | - |
| dc.date.available | 2017-02-07T06:54:31Z | - |
| dc.date.issued | 1998-07 | - |
| dc.identifier.issn | 0975-0975(Online); 0376-4710(Print) | - |
| dc.identifier.uri | http://nopr.niscair.res.in/handle/123456789/40172 | - |
| dc.description | 592-595 | en_US |
| dc.description.abstract | The reaction of S(lV) with pyruvato(pentaamrnine)cobalt(III) has been studied in the range of pH (3.2 - 6.5) and temperatures (15 - 30°C). There is no evidence of substitution of bound carboxylate by sulphite. However, the keto form of the pyruvato complex reacts with HSO3- and SO32- yielding the S(IV) addition product, (NH3)5CoO2CC(SO3)(OH)CH3. The rate constants and activation parameters for both HSO3- and SO3 2- reaction paths are reported. The pyruvato complex and also its sulphite addition product do not undergo reduction of cobalt(III) centre by sulphite. | en_US |
| dc.language.iso | en_US | en_US |
| dc.publisher | NISCAIR-CSIR, India | en_US |
| dc.rights |  CC Attribution-Noncommercial-No Derivative Works 2.5 India | en_US |
| dc.source | IJC-A Vol.37A(07) [July 1998] | en_US |
| dc.title | Kinetics and mechanism of reaction of sulphur(lV) with pyruvate (pentaammine) cobalt(III). | en_US |
| dc.type | Article | en_US |
| Appears in Collections: | IJC-A Vol.37A(07) [July 1998] | |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 37A(7) 592-595.pdf | 375.22 kB | Adobe PDF | View/Open |
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