Please use this identifier to cite or link to this item: http://nopr.niscpr.res.in/handle/123456789/40187
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dc.contributor.authorlyun, J Femi-
dc.contributor.authorMusa, Kabir Y-
dc.contributor.authorAyoko, G Adefikayo-
dc.date.accessioned2017-02-07T08:53:51Z-
dc.date.available2017-02-07T08:53:51Z-
dc.date.issued1995-08-
dc.identifier.issn0975-0975(Online); 0376-4710(Print)-
dc.identifier.urihttp://nopr.niscair.res.in/handle/123456789/40187-
dc.description635-638en_US
dc.description.abstractThe stoichiometry, kinetics and mechanisms of the oxidation of HSCH2CH2OH (1) and HSCH2CH2NH (2) by [(bpy)2H2ORulll)2O4+(bpy=2,2'-bipyridine) to the corresponding disulphides have been investigated in aqueous HCIO4. The oxidation is found to be first order each in reductants and the oxidant and the dependence of the second order rate constants on [H+] approximates to k2=a+b [H+]-1. Results have been rationalized in terms of plausible free radical mechanisms.en_US
dc.language.isoen_USen_US
dc.publisherNISCAIR-CSIR, Indiaen_US
dc.rights CC Attribution-Noncommercial-No Derivative Works 2.5 Indiaen_US
dc.sourceIJC-A Vol.34A(08) [August 1995]en_US
dc.titleOxidation of 2-mercaptoethanol and 2-mercaptoethylamine by [(bpy)2H2ORu III]2O4+ in aqueous mediaen_US
dc.typeArticleen_US
Appears in Collections:IJC-A Vol.34A(08) [August 1995]

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