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http://nopr.niscpr.res.in/handle/123456789/40201| Title: | Cyclic voltammetric studies on the stability of complexes of copper(I) with arylazoimidazole and arylazopyridine systems |
| Authors: | Misra, T K Das, D Sinha, C |
| Issue Date: | Aug-1998 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | The overall thermodynamic stability constants ( log b2) of the reaction Cu(l) + 2L = [CuL2] where Cu(l) is in the form of [Cu(MeCN)4]CIO4 and L= N(l)-aJkyl-2-arylazoimidazole (L1-L3) and 2-(aryhizo)pyridine (L4) have been studied in MeOH, cyclic voltammetrically using the method of Lingane.The data reveal that the p-chloroarylazoheterocycles (c) provide the highest stability and pyridine-substituent ( L4) show greater stability than imidazole derivatives (L1-L3) to the copper(I) complexes. |
| Page(s): | 739-742 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.37A(08) [August 1998] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 37A(8) 739-742.pdf | 384.13 kB | Adobe PDF | View/Open |
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