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http://nopr.niscpr.res.in/handle/123456789/40317| Title: | Ru(lll) catalysed oxidation of a-hydroxy acids by iodate- A kinetic study |
| Authors: | Brahmaiah, A Manikyamba, P |
| Issue Date: | Nov-1995 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | Ru(III) acts as a catalyst in the oxidation of a-hydroxy acids by iodate. The reaction is found to be first order in [oxidant], and [Ru(III)] and fractional order in [hydroxy acid]. H+ ions retard the reaction. A mechanism, involving the formation of a complex between Ru(III) and hydroxy acid which interacts with HIO3 in a slow step, is proposed. |
| Page(s): | 900-903 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.34A(11) [November 1995] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 34A(11) 900-903.pdf | 830.69 kB | Adobe PDF | View/Open |
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