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http://nopr.niscpr.res.in/handle/123456789/40324| Title: | Synthesis of monoligate ditertiary phosphino complexes of niobium(IV) chloride and their bonding interaction with Mo( CO)6 |
| Authors: | Sharma, Sangeeta Sonika Gupta, Shamma Vermani, O P Narula, A K |
| Issue Date: | Nov-1995 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | The reduction of niobium chloride with aluminium or zinc in the presence of various ditertiary phosphines give biligate complexes of the type , while sodium amalgam reduction of NbCI5 give monoligate complexes of the type . The complex [Nb2CI8(dppe)4] on further treatment with Mo(CO)6 yielded heteronuclear bimetallic complex . The complexes have been characterized by elemental analysis, IR and NMR spectral studies. |
| Page(s): | 883-887 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.34A(11) [November 1995] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 34A(11) 883-887.pdf | 1.19 MB | Adobe PDF | View/Open |
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, while sodium amalgam reduction of NbCI5 give monoligate complexes of the type
. The complex [Nb2CI8(dppe)4] on further treatment with Mo(CO)6 yielded heteronuclear bimetallic complex
. The complexes have been characterized by elemental analysis, IR and NMR spectral studies.