Please use this identifier to cite or link to this item: http://nopr.niscpr.res.in/handle/123456789/40330
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dc.contributor.authorReddy, Ch Sanjeeva-
dc.contributor.authorKumar, T Vijaya-
dc.date.accessioned2017-02-10T05:58:59Z-
dc.date.available2017-02-10T05:58:59Z-
dc.date.issued1995-11-
dc.identifier.issn0975-0975(Online); 0376-4710(Print)-
dc.identifier.urihttp://nopr.niscair.res.in/handle/123456789/40330-
dc.description871-877en_US
dc.description.abstractThe oxidation of citric and malic acids by bromate in acidic aqueous solutions is catalysed by aquachlororuthenium complex and the kinetics of the reaction is investigated. The rate law is interpreted by a mechanism involving the oxidation of Ru(lll) to Ru(V) by oxidant (Kt), followed by a complex formation (Kc) between Ru(V) and substrate, which decomposes (kd) to products in a slow rate determining step with regeneration of Ru(lll). All individual rate constants are determined at different temperatures and their activation parameters are also evaluated and discussed.en_US
dc.language.isoen_USen_US
dc.publisherNISCAIR-CSIR, Indiaen_US
dc.rights CC Attribution-Noncommercial-No Derivative Works 2.5 Indiaen_US
dc.sourceIJC-A Vol.34A(11) [November 1995]en_US
dc.titleEvaluation of individual rate constants and activation parameters of acid bromate oxidation of hydroxy acids catalysed by aquachlororuthenium complexen_US
dc.typeArticleen_US
Appears in Collections:IJC-A Vol.34A(11) [November 1995]

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