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http://nopr.niscpr.res.in/handle/123456789/40331| Title: | Kinetics of alkaline hydrolysis of N-p-tolylcinnamohydroxamic acid |
| Authors: | Ghosh, Kallol K. Thakur, Santosh S. |
| Issue Date: | Nov-1998 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | The kinetics and mechanism of the alkaline hydrolysis of N-p-tolylcinnamohydroxamic acid have been studied in 10% (v/v) aqueous - dioxane medium at 55, 65 and 75°C. Enthalpies and entropies of activation have been evaluated. Studies of solvent effects, salt effects and rate acidity function correlations indicate a pathway involving the rate limiting formation of a tetrahedral intermediate which decomposes to give products with water and hydroxide ion catalysis. |
| Page(s): | 1016-1019 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.37A(11) [November 1998] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 37A(11) 1016-1019.pdf | 421.83 kB | Adobe PDF | View/Open |
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