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dc.contributor.authorJain, Usha-
dc.contributor.authorSharma, Madhu-
dc.contributor.authorRani, Ashu-
dc.contributor.authorGupta, Krishna S-
dc.date.accessioned2017-02-10T09:38:17Z-
dc.date.available2017-02-10T09:38:17Z-
dc.date.issued1995-12-
dc.identifier.issn0975-0975(Online); 0376-4710(Print)-
dc.identifier.urihttp://nopr.niscair.res.in/handle/123456789/40357-
dc.description971-975en_US
dc.description.abstractKinetics of copper(II)-catalyzed autoxidation of sulphur(IV), in the form of bisulphite, in acetatebuffered solutions obey the rate law
Robs = k5 [S(IV)] + k6[Cu(ll)][S(lV)]2[H+]-1.
The buffer exerts a slight rate decreasing effect, showing the higher acetato complexes to be less reactive. Substitution of the second sulphite into the coordination sphere of copper(II) appears to be the rate-limiting.
en_US
dc.language.isoen_USen_US
dc.publisherNISCAIR-CSIR, Indiaen_US
dc.rights CC Attribution-Noncommercial-No Derivative Works 2.5 Indiaen_US
dc.sourceIJC-A Vol.34A(12) [December 1995]en_US
dc.titleKinetics and mechanism of copper(ll) catalyzed autoxidation of aqueous sulphur dioxide in acetate buffersen_US
dc.typeArticleen_US
Appears in Collections:IJC-A Vol.34A(12) [December 1995]

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