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http://nopr.niscpr.res.in/handle/123456789/40499| Title: | Kinetics and mechanism of oxidation of aliphatic acetals with N-chlorobenzamide |
| Authors: | Ahamed, K A Basheer |
| Issue Date: | Mar-1997 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | The oxidation kinetics of thirteen aliphatic acetals of normal aliphatic aldehydes and substituted aliphatic aldehydes with aliphatic and substituted aliphatic. as well as with aromatic alcohols by N-chlorobenzamide (NCB) in aqueous acetic acid medium follows first order and zero order dependence in [NCB] and [acetal] respectively and yields the corresponding esters as the main product of oxidation. (H2OCl)+ has been postulated as the oxidizing species. |
| Page(s): | 222-224 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.36A(03) [March 1997] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 36A(3) 222-224.pdf | 314.99 kB | Adobe PDF | View/Open |
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