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http://nopr.niscpr.res.in/handle/123456789/40502| Title: | Effect of γ-irradiation on the oxidation of decyl sulphoxide (DSO) with Ce(IV) in acetic acid-water medium |
| Authors: | Mohanty, S S Bhatta, D |
| Issue Date: | Mar-1997 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | Influence of γ-irradiation (5.0 x 102 K Gy) on the oxidation of decyl sulphoxide (DSO) with Ce(IV) in acetic acid-water medium is studied in the temperature range 308-323 K. The data reveal that the rate of the reaction is enhanced with increase in temperature as well as with increase in concentration of the substrate in both the cases of unirradiated and irradiated samples. The rate limiting step involves the decomposition of the complex, generating free radical species which then give rise to sulphone in subsequent stages-.Irradiation, decelerates the rate of reaction and lowers the activation enthalpy and entropy values marginally. |
| Page(s): | 213-215 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.36A(03) [March 1997] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 36A(3) 213-215.pdf | 311.9 kB | Adobe PDF | View/Open |
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