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http://nopr.niscpr.res.in/handle/123456789/40574| Title: | Reactivities of some energy rich organic orthophosphates towards transition metal ion oxidants |
| Authors: | Gupta, Kalyan Kali Sen Mahapatra, Ambikesh Sanyal, Ankan |
| Issue Date: | Apr-1994 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | The orthophosphates,  and  -glycerophosphates, react with HCrO in HCIO4 medium to give 1:1 intermediates which subsequently decomposes to give products of the reactions. The rate is directly proportional to [H+] in each reaction. Thermodynamic parameters associated with the equilibrium step and the activation parameters associated with the slowest step has been evaluated for each substrate. An attempt has been made to correlate the results obtained earlier with other transition metal ion oxidants. |
| Page(s): | 332-334 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.33A(04) [April 1994] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 33A(4) 332-334.pdf | 688.34 kB | Adobe PDF | View/Open |
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